open access publication

Article, 2024

Assessing fluctuating wind to hydrogen production via long-term testing of solid oxide electrolysis stacks

Applied Energy, ISSN 0306-2619, 1872-9118, Volume 361, Page 122938, 10.1016/j.apenergy.2024.122938

Contributors

Liu, Hua 0000-0002-7124-2889 [1] Høgh, Jens Valdemar Thorvald [1] [2] Blennow, Peter [2] Sun, Xiu-Fu 0000-0001-8503-9745 [1] Zong, Yi 0000-0003-1262-3558 [1] Chen, Ming 0000-0001-6387-3739 (Corresponding author) [1]

Affiliations

  1. [1] Technical University of Denmark
  2. [NORA names: DTU Technical University of Denmark; University; Denmark; Europe, EU; Nordic; OECD];
  3. [2] Topsoe A/S, Haldor Topsøes Alle 1, 2800 Kgs. Lyngby, Denmark
  4. [NORA names: Denmark; Europe, EU; Nordic; OECD]

Abstract

The Danish government plans two energy islands to collect offshore wind power for power distribution and green fuel production. Wind power is often criticized for lacking stability, which challenges downstream fuel synthesis processes. Solid oxide electrolysis cells (SOEC) are promising for green hydrogen production on a commercial scale, but the impact of fluctuating power on SOEC remains uncertain. This paper explores the feasibility of a Wind-SOEC coupled system by conducting a 2104-h durability test with the state-of-the-art Topsoe TSP-1 stack. Three periods of steady operation and two periods of dynamic operation were conducted. Wind power fluctuation was simulated during the dynamic period, and two control strategies were used to handle it. The constant flow (CF) and constant conversion (CC) strategies maintain the feedstock flow rate and conversion ratio of steam-to‑hydrogen, respectively. Compared to steady operation, the stack shows no signs of additional degradation in dynamic operation. Thus, the TSP-1 stack has been proven robust and flexible enough to handle fluctuating wind power supplies under both operation strategies. Further, stack performance during dynamic periods was compared and analyzed by removing degradation effects. Accordingly, SOEC stacks with CC control will consume less external heat than CF to maintain a heat balance. Nevertheless, SOEC systems with CF and CC control strategies may have different efficiency or hydrogen production costs. Tech-economic analyses will be needed to investigate control strategies at the system level.

Keywords

CC control, Danish government, SOEC stack, SOEC system, TSP-1, Topsoe, analysis, balance, cells, commercial scale, constant conversion, constant flow, control, control strategy, conversion, conversion ratio, cost, degradation, degradation effects, distribution, durability, durability test, dynamic operation, dynamic period, effect, efficiency, electrolysis cell, electrolysis stack, energy, energy islands, external heating, feasibility, feedstock, feedstock flow rate, flow, flow rate, fluctuations, fuel production, fuel synthesis process, government, green fuel production, green hydrogen production, heat, heat balance, hydrogen, hydrogen production, hydrogen production cost, impact, investigated control strategies, islands, lack stability, levels, long-term tests, offshore wind power, operation, operation strategy, performance, period, power, power distribution, power fluctuations, power supply, process, production, production costs, rate, ratio, scale, solid oxide electrolysis cells, solid oxide electrolysis stacks, stability, stack, stack performance, steady operation, strategies, supply, synthesis process, system, system level, test, wind, wind power, wind power fluctuations, wind power supply

Funders

  • Danish Energy Agency

Data Provider: Digital Science