open access publication

Article, 2023

Isothermal Heteroepitaxy of Ge1–x Sn x Structures for Electronic and Photonic Applications

ACS Applied Electronic Materials, ISSN 2637-6113, Volume 5, 4, Pages 2268-2275, 10.1021/acsaelm.3c00112

Contributors

Concepción, Omar 0000-0001-8197-7523 (Corresponding author) [1] Søgaard, Nicolaj Brink 0000-0002-6718-0910 [2] Bae, Jin Hee 0000-0003-0723-9893 [1] Yamamoto, Yuji 0000-0003-0928-4356 [3] Tiedemann, Andreas T [1] Ikonić, Zoran [4] Capellini, Giovanni 0000-0002-5169-2823 [3] [5] Zhao, Qing-Tai 0000-0002-2794-2757 [1] Grützmacher, Detlev 0000-0001-6290-9672 [1] Buca, Dan Mihai 0000-0002-3692-5596 [1]

Affiliations

  1. [1] Forschungszentrum Jülich
  2. [NORA names: Germany; Europe, EU; OECD];
  3. [2] Aarhus University
  4. [NORA names: AU Aarhus University; University; Denmark; Europe, EU; Nordic; OECD];
  5. [3] Innovations for High Performance Microelectronics
  6. [NORA names: Germany; Europe, EU; OECD];
  7. [4] University of Leeds
  8. [NORA names: United Kingdom; Europe, Non-EU; OECD];
  9. [5] Roma Tre University
  10. [NORA names: Italy; Europe, EU; OECD]

Abstract

Epitaxy of semiconductor-based quantum well structures is a challenging task since it requires precise control of the deposition at the submonolayer scale. In the case of Ge1-x Sn x alloys, the growth is particularly demanding since the lattice strain and the process temperature greatly impact the composition of the epitaxial layers. In this paper, the realization of high-quality pseudomorphic Ge1-x Sn x layers with Sn content ranging from 6 at. % up to 15 at. % using isothermal processes in an industry-compatible reduced-pressure chemical vapor deposition reactor is presented. The epitaxy of Ge1-x Sn x layers has been optimized for a standard process offering a high Sn concentration at a large process window. By varying the N2 carrier gas flow, isothermal heterostructure designs suitable for quantum transport and spintronic devices are obtained.

Keywords

Sn concentration, Sn content, X-structure, alloy, carrier gas flow, cases, chemical vapor deposition reactor, composition, concentration, content, control, deposition, deposition reactor, design, devices, electron, epitaxial layers, epitaxy, flow, gas flow, growth, heterostructure design, isothermal process, isotherms, lattice, lattice strain, layer, process, processing temperature, pseudomorphic Ge, quantum transport, quantum well structures, reactor, realization, scale, spintronic devices, standard process, strain, structure, submonolayer scale, task, temperature, transport, well structures, window

Funders

  • Deutsche Forschungsgemeinschaft
  • European Commission

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