open access publication

Article, 2023

Pathway toward cost-effective green hydrogen production by solid oxide electrolyzer

Energy & Environmental Science, ISSN 1754-5706, 1754-5692, Volume 16, 5, Pages 2090-2111, 10.1039/d3ee00232b

Contributors

Liu, Hua 0000-0002-7124-2889 [1] Clausen, Lasse Røngaard 0000-0002-5092-889X [1] Wang, Ligang [2] Chen, Ming 0000-0001-6387-3739 [1]

Affiliations

  1. [1] Technical University of Denmark
  2. [NORA names: DTU Technical University of Denmark; University; Denmark; Europe, EU; Nordic; OECD];
  3. [2] North China Electric Power University
  4. [NORA names: China; Asia, East]

Abstract

Green hydrogen by solid oxide electrolyzer (SOEC) will become cheaper than gray hydrogen. The Levelized Cost of Hydrogen (LCOH) will be reduced by heat integration, super grid integration, and SOEC development. Solid oxide electrolysis cell (SOEC) is one way to regulate wind power by producing green hydrogen. However, degradation increases the resistance of SOEC, especially at high current density. This work simulates the heat balance and the degradation process at the system level and compares the Levelized Cost of Hydrogen (LCOH) at different locations through three scenarios: heat integration, super grid connection, and SOEC development. Both heat source and wind power costs are involved in the analysis and optimization of a 5000 kg H 2 per day SOEC recirculating system. The voltage and operating conditions of minimum LCOH are located with a two-stage stochastic optimization approach. As a result, SOEC generates extra ohmic heat and reduces the external heat demand from 29.9 MW to 1.8 MW after degradation. LCOH reduced to $3.60 per kg with heat integration. The super grid will cut the LCOH further to $2.59 per kg. SOEC development will break through the trade-off between current density and degradation, resulting in an LCOH of $2.18 per kg. By 2035, green hydrogen is expected to reach an LCOH of $1.40 per kg and outperform gray hydrogen.

Keywords

MW, analysis, approach, balance, cells, connection, cost, cost of hydrogen, cost-effective green hydrogen production, current density, days, degradation, degradation process, demand, density, development, electrolysis cell, electrolyzer, external heat demand, green hydrogen, green hydrogen production, grey hydrogen, grid, grid integration, grid-connected, heat, heat balance, heat demand, heat integration, heat source, hydrogen, hydrogen production, integration, levelized cost, levelized cost of hydrogen, levels, location, ohmic heating, operating conditions, optimization, optimization approach, pathway, power, power cost, process, production, recirculation system, regulating wind power, resistance, results, scenarios, solid oxide electrolysis cells, solid oxide electrolyzer, source, stochastic optimization approach, super grid, system, system level, trade-offs, two-stage stochastic optimization approach, voltage, wind, wind power, wind power cost

Funders

  • China Scholarship Council
  • Innovation Fund Denmark

Data Provider: Digital Science